Preheat the oven to 350 degrees F, and prepare a 9x13 baking dish with cooking spray.
Cook elbow macaroni according to box directions in salted water, but cut the cook time 2 minutes short of al dente (approximately 7 minutes). Reserve 1/4 cup of pasta water, then drain.
While macaroni cooks, shred the cheeses, then add 1 cup each of mozzarella, monterey jack and sharp cheddar to a medium mixing bowl. Toss to combine. Reserve 1 cup of sharp cheddar for topping.
After draining and while macaroni is still hot, add to bowl with cheese and mix gently to combine. Set aside.
In a second bowl (large and microwave-safe), melt the butter in the microwave (approx. 30 seconds), then add the sour cream and milk. Whisk to combine.
Next, add the eggs to the same bowl, whisking to combine until smooth.
Drain the canned corn, then add to the same bowl, mixing to combine.
In a separate small bowl, combine the flour, cornmeal, baking powder, sugar, salt, mustard powder and cayenne pepper.
Add the dry ingredients to the bowl with the corn, whisking until smooth.
Add cheesy macaroni to the bowl with the corn, and mix gently with a spoon until combined. Use reserved pasta water to thin out the consistency slightly if needed.
Pour mixture into greased baking dish, and top with remaining sharp cheddar cheese.
Bake at 350 degrees F for 40-45 minutes, or until cheese is golden brown on top.